Abstract We study Hopf classes: families of pure ordered simplicial complexes that give rise to Hopf monoids under join and deletion/contraction. The prototypical Hopf class is the family of ordered matroids. The idea of a Hopf class leads to a systematic study of simplicial complexes related to matroids, including shifted complexes and broken-circuit complexes. We compute the Hopf antipodes in two cases: facet-initial complexes (which generalize shifted complexes) and unbounded ordered matroids. The latter calculation uses the topological method of Aguiar and Ardila, complicated by certain auxiliary simplicial complexes that we call Scrope complexes, whose Euler characteristics control the coefficients of the antipode. The resulting antipode formula is multiplicity-free and cancellation-free.