Results are reported for a survey of asteroids at 0.56, 1.6, and 2.2 microns. The observations of 30 asteroids are reduced to relative reflectances at 1.6 and 2.2 microns (such that the relative reflectance at 0.56 micron is scaled to unity). These relative reflectances have important implications for the classification of asteroids. Low-albedo asteroids show a significant range in their infrared relative reflectances, but carbonaceous chondritic-type material remains a good candidate for their surface composition. Many S-type asteroids are found to have significantly brighter infrared relative reflectances than M-type asteroids. Lunarlike dark glass on the surfaces of these objects is probably ruled out. A metallic phase is the most plausible candidate, which implies a multiple-component surface composition perhaps similar to certain stony-iron meteorites. The data suggest that such a metallic phase may be common in the inner asteroid belt.