Due to the high steam velocity and low thermal parameters at the turbine's final stage, steam generates non-equilibrium condensation and forms a large number of small droplets during the process of pressure expansion. The wet steam mixed with droplets impinges on the turbine blades, endangering turbine operation safety and reducing turbine work efficiency. This article modifies the non-equilibrium condensation control equation and embeds it into the numerical simulation software to make the numerical calculation results more accurate. By modifying the inlet steam superheat in the classical experiments, the condensation characteristics of wet steam in Moses–Stein nozzles and Dykas cascades are studied. The results show that increasing inlet superheat can effectively suppress the generation of non-equilibrium condensation and reduce outlet liquid mass fraction. The minimum supercooling temperature of non-equilibrium condensation is only related to the working fluid characteristics (the steam model used in this article is around 20 K). When the inlet superheat of the cascade is large, the rapid condensation region is mainly near the suction surface. In contrast, when the superheat is low, the rapid condensation zone is mainly near the pressure surface. The condensation location is mainly affected by the intensity of internal condensation shock waves in the cascade. Increasing inlet superheat not only increases the shock wave intensity but also decreases the shock wave angle in the passage. When the inlet temperature increases by 20 K, the heat efficiency of the cascade increases by about 1%.