
arXiv: 1709.06852
On the assumption that experimentally validated tabulated thermodynamic properties of saturated fluids published by the National Institute of Standards and Technology are accurate, a theoretical thermodynamic cycle can be demonstrated that produces a net-negative entropy generation to the universe. The experimental data on the internal energy can also be used to obtain a simple, empirical equation for the change in internal energy of a real fluid undergoing isothermal expansion and compression. This demonstration provides experimental evidence to the theory that temperature-dependent intermolecular attractive forces can be an entropic force that can enhance the thermodynamic efficiency of a real-fluid macroscopic heat engine to exceed that of the Carnot efficiency.
Chemical Physics (physics.chem-ph), Physics, QC1-999, Physics - Chemical Physics, FOS: Physical sciences
Chemical Physics (physics.chem-ph), Physics, QC1-999, Physics - Chemical Physics, FOS: Physical sciences
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