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The Journal of Chemical Physics
Article
License: CC BY NC SA
Data sources: UnpayWall
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CONICET Digital
Article . 2014
License: CC BY NC SA
Data sources: CONICET Digital
The Journal of Chemical Physics
Article . 2014 . Peer-reviewed
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Star polymers rupture induced by constant forces

Authors: García, Nicolás; Febbo, Mariano; Vega, Daniel Alberto; Milchev, A.;

Star polymers rupture induced by constant forces

Abstract

In this work, we study the breakage process of an unknotted three-arm star-shaped polymer when it is pulled from its free ends by a constant force. The star polymer configuration is described through an array of monomers coupled by anharmonic bonds, while the rupture process is tracked in three-dimensional space by means of Langevin Molecular Dynamics simulations. The interaction between monomers is described by a Morse potential, while a Weeks-Chandler-Anderson energetic contribution accounts for the excluded volume interaction. We explore the effect of the molecular architecture on the distributions of rupture times over a broad interval of pulling forces and star configurations. It was found that the rupture time distribution of the individual star arms is strongly affected by the star configuration imposed by the pulling forces and the length of the arms. We also observed that for large pulling forces the rupture time distributions resemble the dominant features observed for linear polymer chains. The model introduced here provides the basic ingredients to describe the effects of tensile forces on stress-induced degradation of branched macromolecules and polymer networks.

Country
Argentina
Keywords

STAR POLYMERS, THERMOMECHANICAL EFFECTS, https://purl.org/becyt/ford/1.3, MOLECULAR DYNAMICS, BREAKAGE OF POLYMERS CHAINS, https://purl.org/becyt/ford/1

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
Green
hybrid