Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

Raman light scattering from supracritical binary fluid mixtures: CH4/CF4

Authors: F. G. Baglin; S. Sweitzer; W. Stanbery;

Raman light scattering from supracritical binary fluid mixtures: CH4/CF4

Abstract

A supracritical fluid mixture of CH4/CF4 (1:9 mole ratio) has been studied at 323 K at densities between 3.0 and 19.1 mol -ℓ (m/ℓ) by inelastic (Raman) light scattering originating from the ν1 totally symmetric stretching mode of methane. Furthermore, a Raman depolarization ratio study of the integrated intensities of the ν1 mode was also carried out as a function of density. A model is proposed to aid in the understanding of the intensity-density behavior in terms of both allowed and interaction-induced (ii) contributions to the overall observed signal. The model makes use of one, two, and three body light scattering via both the dipole polarizability, the dipole–quadrupole polarizability, and also takes into account various partner combinations in the multibody light scattering. Whereas, the model generally predicts correct Iνh behavior, (here I is the Raman intensity and the subscripts refer to the vertical polarization direction of the laser (ν) and the direction of the analyzer either ν or h (horizontal)), it is shown that the standard assumption of the no V–R coupling is violated, leading to a different mechanism for Iiso Raman light scattering. This leads to extensive three-body ii Iiso signal cancellation, but none from the Iνh spectrum. The model adequately explains these concepts through the usual interaction induced processes as well as a unique cross term.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    4
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
4
Average
Average
Average
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!