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The Journal of Chemical Physics
Article . 2012 . Peer-reviewed
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2012
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
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Fluorescence quenching near small metal nanoparticles

Authors: Pustovit, Vitaliy N.; Shahbazyan, Tigran V.;

Fluorescence quenching near small metal nanoparticles

Abstract

We develop a microscopic model for fluorescence of a molecule (or semiconductor quantum dot) near a small metal nanoparticle. When a molecule is situated close to metal surface, its fluorescence is quenched due to energy transfer to the metal. We perform quantum-mechanical calculations of energy transfer rates for nanometer-sized Au nanoparticles and find that nonlocal and quantum-size effects significantly enhance dissipation in metal as compared to those predicted by semiclassical electromagnetic models. However, the dependence of transfer rates on molecule's distance to metal nanoparticle surface, d, is significantly weaker than the d−4 behavior for flat metal surface with a sharp boundary predicted by previous calculations within random phase approximation.

Keywords

Condensed Matter - Mesoscale and Nanoscale Physics, Metal Nanoparticles, FOS: Physical sciences, Fluorescence, Energy Transfer, Models, Chemical, Quantum Dots, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), Gold, Algorithms, Fluorescent Dyes

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    popularity
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    Top 10%
    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
63
Top 10%
Top 10%
Top 10%
Green
bronze