Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

Excited electronic states of the tropyl (cyclo-C7H7 ) radical

Authors: Russell D. Johnson;

Excited electronic states of the tropyl (cyclo-C7H7 ) radical

Abstract

Two-photon electronic absorption spectra of the tropyl radical (cyclic C7H7 ) have been observed by resonance enhanced multiphoton ionization spectroscopy (REMPI) from 415 to 590 nm, corresponding to 34 000–48 000 cm−1. Two Rydberg series are assigned and an ionization potential determined: np, δ=0.35; nf, δ=0.05; I.P.=50 177 cm−1. Vibrational activity of the Rydberg states was observed and the frequencies were found to be similar to the ion: ω2=862 cm−1 (ring breathing); 2ω18=1528 cm−1 (ring bending); and 2ω20=1284 cm−1 (CH out-of-plane bend).

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    15
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Average
Top 10%
Average
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!