Stimulated emission spectroscopy of the ground state of Na3

descriptionPublicationkeyboard_double_arrow_right Article 15 Apr 1989 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 90, pages 4,620-4,622 (issn: 0021-9606, eissn: 1089-7690,

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Authors: M. Broyer; G. Delacrétaz; G.-Q. Ni; R. L. Whetten; J.-P. Wolf; L. Wöste;

doi: 10.1063/1.456599

Stimulated emission spectroscopy of the ground state of Na3

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Abstract

The vibronic level spectrum of the ground state of the alkali trimer Na3 has been observed via stimulated emission spectroscopy of a supercooled metal cluster beam. Results reported herein use the C state as an intermediate, and reveal strong transitions to combinations of the symmetric stretch and bending modes, along with highly detailed fine structure.

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