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Rotational tunneling in CH4 under pressure (CH4 III)

Authors: M. Prager; W. Press; A. Heidemann; C. Vettier;

Rotational tunneling in CH4 under pressure (CH4 III)

Abstract

High resolution neutron inelastic scattering techniques were used to measure tunneling spectra of methane (CH4) in its phase III. By increasing the pressure from 0.6 to 1.8 kbar the tunneling lines shift by about a factor of 1.5. The rather complicated spectra can be equally well described by two simple structural models. Both contain two inequivalent molecular sites of low symmetry. They already have provided a rather good fit of the spectrum of CD4 III. An exponent n = 8±2 of an effective intermolecular potential V∼r−n is obtained by analyzing the pressure dependence of the tunneling frequencies.

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
29
Average
Top 10%
Top 10%
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