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Collective effects in physical adsorption

Authors: F. Delanaye; M. Schmeits; A. A. Lucas;

Collective effects in physical adsorption

Abstract

The collective electronic polarization waves occurring in a regular two-dimensional lattice of rare gas atoms adsorbed on a metallic surface are studied, including interactions mediated by the metallic substrate. The atoms are represented as three-dimensional isotropic harmonic oscillators interacting via electrostatic dipolar forces. The polarization eigenmodes of an isolated monolayer are first determined, from which the cohesive energy of the layer can be deduced from the total zero-point energy of the modes. Then the role of the substrate is introduced by treating the metal first as a perfectly conducting medium (ε=−∞) and then, more appropriately, as a substrate of dynamical dielectric function ε (ω) =1−ω2p/ω2. The monolayer–metal interaction produces a shift of the collective atomic frequencies and of the metal surface plasmon frequencies. From the zero-point energy shift, one obtains an expression of the total interaction energy. Numerical applications are made for a square lattice of Kr adsorbed on metals of various plasmon frequencies.

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
17
Average
Top 10%
Top 10%
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