
doi: 10.1063/1.2778747
We studied the thermoelectric properties of BaSi2, SrSi2, and LaSi. The polycrystalline samples were prepared by spark plasma sintering (SPS). The electrical resistivity (ρ), Seebeck coefficient (S), and thermal conductivity (κ) were measured above room temperature. The power factor (S2∕ρ) is quite low (below 10−5 Wm−1 K−2 over the whole temperature range) for BaSi2 and LaSi, while relatively high (1.19×10−3 Wm−1 K−2 at 331 K) for SrSi2. BaSi2 exhibits quite low κ. The κ values at room temperature are 1.56, 5.25, and 6.71 Wm−1 K−1 for BaSi2, SrSi2, and LaSi, respectively. The maximum values of the dimensionless figure of merit, ZT=S2T∕ρ∕κ, are 0.01 at 954 K for BaSi2, 0.09 at 417 K for SrSi2, and 0.002 at 957 K for LaSi.
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