Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

Chromium Ion Pair Interactions in the Paramagnetic Resonance Spectrum of Ruby

Authors: H. Statz; L. Rimai; M. J. Weber; G. A. deMars; G. F. Koster;

Chromium Ion Pair Interactions in the Paramagnetic Resonance Spectrum of Ruby

Abstract

The paramagnetic resonance spectrum of Cr3+ pairs in ruby which interact via exchange and dipolar forces have been studied at 15.74 kMc in the temperature range 1.2° to 700°K. Theoretical analysis predicts and experiments confirm that relatively distant neighbors with negligible exchange coupling give rise to resonance lines which cluster around isolated Cr3+ ion lines. Spin pairs coupled through exchange forces large as compared to the Zeeman or crystalline field energies give rise to lines that cluster around magnetic field values different from those for isolated Cr3+ lines. Exact calculations on an IBM 704 computer are used to assign lines in a given cluster to various neighbor pairs. This assignment together with the temperature dependence of the line intensities are used to determine the exchange forces. For nearest neighbors the exchange constant is 390±50 cm−1 while the 3rd through 11th neighbor shells have exchange interactions of order 1 cm−1. Spin-lattice relaxation is discussed for pairs coupled through anisotropic exchange or weak isotropic exchange forces.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    66
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
66
Average
Top 1%
Top 10%
Related to Research communities
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!