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Theoretical Calculations of the Kinetics of the Order–Disorder Transition in Carbon Monoxide and of the Energy Levels of a Double-Minimum Two-Dimensional Hindered Rotor

Authors: R. F. Curl; H. P. Hopkins; Kenneth S. Pitzer;

Theoretical Calculations of the Kinetics of the Order–Disorder Transition in Carbon Monoxide and of the Energy Levels of a Double-Minimum Two-Dimensional Hindered Rotor

Abstract

The kinetics of the order–disorder transition in solid carbon monoxide by a tunneling mechanism are considered. The rate of the transition is found to be much smaller than the rate of barrier penetration. An estimate of the rate is made using the best current estimate of the twofold barrier to end-for-end rotation in solid carbon monoxide; it appears that the rate of ordering will be unobservably slow. The rate is very sensitive to the barrier height and might become observable if the barrier were smaller by a factor of 2. The energy levels of the two-dimensional double-minimum hindered rotor have been calculated as a function of barrier height and are tabulated.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
56
Average
Top 10%
Top 10%
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