
doi: 10.1039/c4ra08116a
The colour changing temperature of the thermo-solvatochromic solution of a chloro-nickel complex, di-(1-butyl-3-methylimidazolium) tetrachloronickelate, [bmim]2NiCl4 (0.14 mol L−1 in the photograph), in 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate, [C2OHmim]BF4, can be continuously decreased from above room temperature to well below 0 °C simply by addition of excess [bmim]Cl (1.4 mol L−1 in the photograph), bringing about unprecedented cryo-solvatochromism in ionic liquids.
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