
A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.
Sensitized Solar-Cells, Light, Photoinduced Hydrogen-Production, Photochemistry, Discrete, Rhodium, Photophysical Properties, Metallomacrocycles, Phosphorescent Emission Aipe, Construction
Sensitized Solar-Cells, Light, Photoinduced Hydrogen-Production, Photochemistry, Discrete, Rhodium, Photophysical Properties, Metallomacrocycles, Phosphorescent Emission Aipe, Construction
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