MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions

descriptionPublicationkeyboard_double_arrow_right Article 08 Aug 2002 France Publisher:Royal Society of Chemistry (RSC)Journal:Physical Chemistry Chemical Physics, volume 4, pages 4,435-4,443 (issn: 1463-9076, eissn: 1463-9084,

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Authors: Papaiconomou, N.; Simonin, J.-P.; Bernard, Olivier; Kunz, W.;

doi: 10.1039/b204841h

MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions

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Abstract

The mean spherical approxn. (MSA) approach for electrolyte solns. is combined with a modified non-random two-liq. (NRTL) approach. The resulting model is suitable for a description of the thermodn. properties of electrolyte-multisolvent systems. The ability of this MSA-NRTL model is investigated by examg. activity and osmotic coeffs. of binary and ternary electrolyte solns. Esp. for non-aq. solns., the model is superior to std. semi-empirical calcns. used in the chem. industry.

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France

Related Organizations

Sorbonne University
France
French National Centre for Scientific Research
France
ESPCI Paris
France
Sorbonne Université
France
PSL Research University
France

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Keywords

[CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistry

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