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New insight into the potential oscillations during iodate reduction in alkaline solution

Authors: Li, ZL; Cai, JL; Zhou, SM;

New insight into the potential oscillations during iodate reduction in alkaline solution

Abstract

Potential oscillations during the reduction of iodate ions in alkaline solution under galvanostatic conditions have been re-investigated without adding iodide. The oscillations can take place only when the applied current is larger than the limiting current, and the oscillation amplitudes are within the plateau region of the limiting current. The bistability, i.e., iodate reduction and hydrogen evolution at different potentials, coupled with convection feedback, induced by hydrogen evolution, accounts for the oscillations. The mechanism was supported by the experimental results of current sweep and cyclic voltammetry. Our study shows that physical processes, i.e., alternately predominant mass transfer of the iodate by diffusion and by convection, play an important role in the oscillations.

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China (People's Republic of)
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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Average
Top 10%
Top 10%
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