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Magnetic hyperfine interactions in the Zintl phase EuZnSn

Authors: Uta Ernet; Ralf Müllmann; Bernd D. Mosel; Hellmut Eckert; Rainer Pöttgen; Gunter Kotzyba;

Magnetic hyperfine interactions in the Zintl phase EuZnSn

Abstract

Magnetic susceptibility, 119 Sn and 151 Eu Mossbauer effect measurements are reported for the Zintl phase EuZnSn which crystallizes with the TiNiSi-type structure. The stannide shows Curie–Weiss behaviour above 40 K with an experimental magnetic moment of µ exp =7.88(5) µ B /Eu, close to that of the free Eu 2+ ion of µ eff =7.94 µ B . At 20.5(2) K a magnetic phase transition to the antiferromagnetic state is observed in the temperature dependence of the inverse susceptibility at a magnetic flux density of 0.01 T. Magnetization measurements at 5 K indicate metamagnetism with a saturation magnetic moment of 6.80(5) µ B /Eu and a critical field of 0.7(1) T. 151 Eu Mossbauer measurements show an isomer shift δ=-10.9 mm s -1 against EuF 3 , as is typically observed for divalent europium. While onset of magnetic ordering is evident at T 0 =26.5(5) K, full magnetic order is detected near 15 K. 119 Sn Mossbauer spectra show a large transferred magnetic field of 12.8 T at 4.2 K. The temperature dependence of this field is closely correlated with the internal magnetic field measured at the 151 Eu site (23.4 T at 4.2 K).

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
24
Top 10%
Top 10%
Top 10%
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