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Mn2+ activated Ca-α-SiAlON – broadband deep-red luminescence and sensitization by Eu2+, Yb2+ and Ce3+

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jan 2021 Netherlands English Publisher:Royal Society of Chemistry (RSC)Journal:Materials Advances, volume 2, pages 2,075-2,084 (eissn: 2633-5409,

Authors: Andries Meijerink; Sadakazu Wakui; Sadakazu Wakui; Arnoldus J. van Bunningen; Atul D. Sontakke;

doi: 10.1039/d1ma00036e

Mn2+ activated Ca-α-SiAlON – broadband deep-red luminescence and sensitization by Eu2+, Yb2+ and Ce3+

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Abstract

Mn2+ occupies [Ca(N,O)7] polyhedral site in Ca-α-SiAlON. The polyhedral site imposes stronger crystal field and nephelauxetic shift on Mn2+ 4T1 → 6A1 transition, leading to an intense and broad deep-red emission.

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