AbstractTriboelectric nanogenerators have received significant research attention in recent years. Structural design plays a critical role in improving the energy harvesting performance of triboelectric nanogenerators. Here, we develop the magnetic capsulate triboelectric nanogenerators (MC-TENG) for energy harvesting under undesirable mechanical excitations. The capsulate TENG are designed to be driven by an oscillation-triggered magnetic force in a holding frame to generate electrical power due to the principle of the freestanding triboelectrification. Experimental and numerical studies are conducted to investigate the electrical performance of MC-TENG under cyclic loading in three energy harvesting modes. The results indicate that the energy harvesting performance of the MC-TENG is significantly affected by the structure of the capsulate TENG. The copper MC-TENG systems are found to be the most effective design that generates the maximum mode of the voltage range is 4 V in the closed-circuit with the resistance of 10 GΩ. The proposed MC-TENG concept provides an effective method to harvest electrical energy from low-frequency and low-amplitude oscillations such as ocean wave.