Oxidation of Olefins by Chromic Acid

descriptionPublicationkeyboard_double_arrow_right Article 20 Sep 1947 English Publisher:Springer Science and Business Media LLCJournal:Nature, volume 160, pages 402-402 (issn: 0028-0836, eissn: 1476-4687,

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Authors: A. BYERS; W. J. HICKINBOTTOM;

doi: 10.1038/160402a0

Oxidation of Olefins by Chromic Acid

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Abstract

The oxidation of 2:4: 4-trimethylpentene-1 [α–diisobutylene] [I] by chromium tri-oxide dissolved in acetic anhydride yields a neutral oil containing largely 2: 4: 4-trimethylpentan-1: 2-epoxide [II] with smaller amounts of 2: 2-dimethylpentanone-4. [V], 2: 4: 4-trimethylpentanal [III] with 2: 4: 4-trimethylpentan-1: 2-diol [IV] and unsaturated alcohols partly as acetates.

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University of Birmingham
United Kingdom

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