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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Utrecht University R...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
The Journal of Physical Chemistry C
Article . 2009 . Peer-reviewed
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Size Dependence of the Spontaneous Emission Rate and Absorption Cross Section of CdSe and CdTe Quantum Dots

Authors: de Mello Donega, C.; Koole, R.;

Size Dependence of the Spontaneous Emission Rate and Absorption Cross Section of CdSe and CdTe Quantum Dots

Abstract

In this paper, the size dependence of the band gap, of the spontaneous emission rate, and of the absorption cross section of quantum dots is systematically investigated over a wide size range, using colloidal CdSe and CdTe QDs as model systems (diameters ranging from 1.2 to 8 nm and from 2 to 9.5 nm, respectively). The size dependence of the band gap is well-described by theoretical models, and is dominated by the quantum confinement contribution (1/d2 scaling). The spontaneous emission rate increases linearly with the emission frequency for both CdSe and CdTe QDs, in good agreement with theoretical predictions. By extrapolating the frequency dependence of the emission rates to the bulk band gap values, the exciton radiative lifetime in bulk CdSe and CdTe could be estimated for the first time (viz., 18 and 20 ns, respectively). Comparison between the empirical trends and theoretical predictions provides new fundamental insights into the size dependence of the 1S(e)1S3/2(h) oscillator strengths of QDs, both for emission and absorption. The results highlight the importance of the balance between quantum confinement and coulomb interaction contributions to the size dependence of the exciton properties in QDs and offer an explanation to the long-standing discrepancies observed between the empirical size-dependent trends and the theoretical predictions. The difference between the size dependence of the radiative decay rates and of the absorption cross sections is shown to be due to the fundamental differences between the emission and absorption transitions (viz., spontaneous versus stimulated). The results are also relevant from a practical viewpoint, since they show that the molar extinction coefficients at energies far above the band gap are better suited for analytical purposes. Moreover, more extended and accurate sizing curves are provided for CdSe and CdTe QDs.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
198
Top 1%
Top 10%
Top 1%
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