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Article . 2011 . Peer-reviewed
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Article . 2011
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The Journal of Physical Chemistry B
Article . 2011 . Peer-reviewed
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Convective Mixing Induced by Acid–Base Reactions

Authors: Almarcha, Christophe; R'Honi, Y.; de Decker, Y.; Trevelyan, P. M. J.; Eckert, K.; de Wit, A.;

Convective Mixing Induced by Acid–Base Reactions

Abstract

When two miscible solutions, each containing a reactive species, are put in contact in the gravity field, local variations in the density due to the reaction can induce convective motion and mixing. We characterize here both experimentally and theoretically such buoyancy-driven instabilities induced by the neutralization of a strong acid by a strong base in aqueous solutions. The diverse patterns obtained are shown to depend on the type of reactants used and on their relative concentrations. They have their origin in a combination of classical hydrodynamic instabilities including differential diffusion of the solutes involved while temperature effects only play a marginal role.

Countries
Belgium, France
Keywords

FRONTS, POROUS-MEDIA, INSTABILITY, REACTION-DIFFUSION PROCESS, Chimie théorique, Chimie des surfaces et des interfaces, DRIVEN, Physico-chimie générale, CHEMICAL WAVES, SYSTEMS, HELE-SHAW CELL, Chimie, Cinétique chimique, INTERFACES, PATTERN-FORMATION

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    54
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
54
Top 10%
Top 10%
Top 10%
Green