The Phase Diagram of the Cerium-Cerium Trichloride System

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1959 English Publisher:American Chemical Society (ACS)Journal:The Journal of Physical Chemistry, volume 63, pages 1,110-1,112 (issn: 0022-3654, eissn: 1541-5740,

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Authors: G. W. Mellors; S. Senderoff;

doi: 10.1021/j150577a017

The Phase Diagram of the Cerium-Cerium Trichloride System

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Abstract

The solubility of cerium in cerium trichloride is 9.3 mole% with a temperature coefficient of nearly zero between 777 and 950 deg C. The solubility of CeCl/sub 3/ in ceis not greater than 0.2 mole % at 950 EC. Above 777 deg C and 9.3 mole% added cerium the system consists of two immiscible liquids in equilibrium and has a consolute temperature that is too high to estimate from these data. The data from thermal and chemical analysis reported are consistent with e.m.f. measurements on the system reported previously. (auth)

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