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Low-temperature polarized and time-resolved photoluminescence spectroscopy in high magnetic fields (up to 30 T) has been used to study the spin-polarization, spin-relaxation, and radiative lifetimes of excitons in wurtzite semiconductor (e.g., CdSe) colloidal nanocrystals. The applied magnetic field leads to a significant degree of circular polarization of the exciton photoluminescence, accompanied by a reduction in the photoluminescence decay time. The circular polarization arises from the Zeeman splitting of exciton levels, whereas lifetime reduction results from a polarization-preserving field-induced mixing of exciton levels. We analyze these experimental findings in terms of a simple model that combines both Zeeman effect and exciton-level mixing, as a function of the relative orientation of the nanocrystal c-axis and the magnetic field. This model is able to simultaneously describe the degree of circular polarization and lifetime reduction of the exciton photoluminescence, permitting us to quantify the exciton, electron, and hole g-factors.
Soft Condensed Matter & Nanomaterials (HFML), nanocristal, Taverne, Correlated Electron Systems / High Field Magnet Laboratory (HFML)
Soft Condensed Matter & Nanomaterials (HFML), nanocristal, Taverne, Correlated Electron Systems / High Field Magnet Laboratory (HFML)
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 17 | |
popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 10% | |
influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |