AbstractBased on very deep photometry, Surface Brightness Fluctuations (SBF) have been traditionally used to determine galaxy distances. We have recently computed SBF spectra of stellar populations at moderately high resolution, which are fully based on empirical stars. We show that the SBF spectra provide an unprecedented potential for stellar population studies that, so far, have been tackled on the basis of the mean fluxes. We find that the SBFs are able to unveil metal-poor stellar components at the one percent level, which are not possible to disentangle with the standard analysis. As these metal-poor components correspond to the first stages of the chemical enrichment, the SBF analysis provides stringent constrains on the quenching epoch.