Formation of glucoraphanin by chemoselective oxidation of natural glucoerucin: A chemoenzymatic route to sulforaphane
Copyright policy )Formation of glucoraphanin by chemoselective oxidation of natural glucoerucin: A chemoenzymatic route to sulforaphane
A new semi-synthetic way to produce glucoraphanin (2), the bio-precursor of the potential anticarcinogen sulforaphane (3), has been developed. Starting from glucoerucin (1), isolated from ripe seeds of Eruca sativa, glucoraphanin was obtained through chemoselective oxidation. Controlled myrosinase-catalysed hydrolysis of this precursor quantitatively afforded sulforaphane.
Magnetic Resonance Spectroscopy, Glycoside Hydrolases, Glucosinolates, Catalysis, Glucose, Isothiocyanates, Sulfoxides, Imidoesters, Oximes, Oxidation-Reduction, Chromatography, High Pressure Liquid, Thiocyanates
Magnetic Resonance Spectroscopy, Glycoside Hydrolases, Glucosinolates, Catalysis, Glucose, Isothiocyanates, Sulfoxides, Imidoesters, Oximes, Oxidation-Reduction, Chromatography, High Pressure Liquid, Thiocyanates
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