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Science Bulletin
Article
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Science Bulletin
Article . 2021 . Peer-reviewed
License: Elsevier TDM
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A robust, highly reversible, mixed conducting sodium metal anode

Authors: Cao, Keshuang; Ma, Qianli; Tietz, Frank; Xu, Ben Bin; Yan, Mi; Jiang, Yinzhu;

A robust, highly reversible, mixed conducting sodium metal anode

Abstract

Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries, but severely suffers from fatal dendrite growth accompanied with huge volume change. Herein, a robust mixed conducting sodium metal anode is designed through incorporating NaSICON-type solid Na-ion conductor into bulk Na. A fast and continuous pathway for simultaneous transportation of electrons and Na+ is established throughout the composite anode. The intimate contact between Na-ion conducting phase and Na metallic phase constructs abundant two-phase boundaries for fast redox reactions. Further, the compact configuration of the composite anode substantially protects Na metal from being corroded by liquid organic electrolyte for the minimization of side reactions. Benefiting from the unique configuration, the composite anode shows highly reversible and durable Na plating/stripping behavior. The symmetric cells exhibit ultralong lifespan for over 700 h at 1 mA cm-2 with a high capacity of 5 mAh cm-2 and outstanding rate capability up to 8 mA cm-2 in the carbonate electrolyte. Full cells with Na3V2(PO4)3/C cathode demonstrate impressive cycling stability (capacity decay of 0.012% per cycle) and low charge/discharge polarization as well. This work provides new insights into rational design and development of robust sodium metal anode through an architecture engineering strategy for advanced rechargeable sodium batteries.

Country
Germany
Keywords

H600, info:eu-repo/classification/ddc/500

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    37
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
37
Top 10%
Top 10%
Top 10%
Green
bronze