The formation of ZnSe via a mechanically-induced self-sustaining reaction (MSR) from a Zn/Se mixture showed that only size reduction and mixing of the reactants without product formation occurred during the induction period prior to ignition. Therefore, all mechanical energy supplied by the planetary mill during this time, called the ignition time (t ig), was used exclusively in the activation of the reactants. This system was chosen to study the dependence of t ig on the main parameters characterising the milling intensity of planetary mills. The variation of the ignition time with the process conditions reflected changes in the mechanical dose rate of the planetary mill. A direct relationship between the inverse of the ignition time and the power of the planetary mill was established, which allows the validation of theoretical models proposed in the literature for the energy transfer in milling devices and the comparison of milling equipment efficiencies

Gobierno de España No. MAT2011-22981

CSIC No. 2009SK0002