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Hal
Article . 2014
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Polymer
Article . 2014 . Peer-reviewed
Data sources: Crossref
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The apparent activation energy and dynamic fragility of ancient ambers

Authors: Jing Zhao; Gregory B. McKenna;

The apparent activation energy and dynamic fragility of ancient ambers

Abstract

Abstract According to the literature, different types of materials have different glass transition temperature ( T g ) dependences of apparent activation energy ( E g ) and dynamic fragility ( m ). In previous work we found that for different ambers, there were different glass transition temperatures. These same samples provide an opportunity to study the T g dependence of E g and m for amber, which has not been reported previously in the literature. In this work, nine pieces of amber from different locations and having different ages were investigated by differential scanning calorimetry. Six cooling rates were used to provide the different thermal histories, and the corresponding limiting fictive temperatures were determined using Moynihan's area matching method. From the cooling rate dependence of the limiting fictive temperature both the apparent activation energy and dynamic fragility were calculated. We find that as glass transition temperature increases, both the apparent activation energy and dynamic fragility increase. The T g dependence of m for amber shows a similar trend with temperature as do the metallic glass formers and compares favorably with the m – T g dependence of other aromatic polymers.

Keywords

[CHIM.POLY] Chemical Sciences/Polymers, [SPI] Engineering Sciences [physics], [CHIM] Chemical Sciences, [SPI.MAT] Engineering Sciences [physics]/Materials, [PHYS.COND] Physics [physics]/Condensed Matter [cond-mat], [PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], [PHYS] Physics [physics]

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
24
Top 10%
Top 10%
Top 10%
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