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Polymer
Article . 2004 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Effects of the degree of undercooling on flow induced crystallization in polymer melts

Authors: COPPOLA S.; BALZANO L.; GIOFFREDI E.; MAFFETTONE P. L.; GRIZZUTI, NINO;

Effects of the degree of undercooling on flow induced crystallization in polymer melts

Abstract

This study investigates the coupled effects of mild shear flow and temperature on the crystallization behavior of two thermoplasticpolymers, namely, an isotactic polypropylene and an isotactic poly(1-butene). Rheological experiments are used to measure thecrystallization induction time under isothermal, steady shear flow conditions. The experimental results clearly show the effects of the degreeof undercooling on flow-induced crystallization (FIC). As temperature decreases, the corresponding increase in chain orientation at a givenshear rate leads to an absolutely faster crystallization. At the same time, however, a temperature decrease makes the flow-induced drivingforce to crystallization relatively less influent with respect to the intrinsic kinetics. A FIC model based on the Doi–Edwards microrheologicaltheory is shown to successfully describe the quantitative details of the observed experimental behavior.

Countries
Italy, Netherlands
Keywords

polymer, flow induced crystallization; polymer; rheology, rheology, flow induced crystallization

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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
85
Top 10%
Top 10%
Top 10%
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