Connectivity is a homotopy invariant property of separable C*-algebras which has three notable consequences: absence of nontrivial projections, quasidiagonality and a more geometric realization of KK-theory for nuclear C*-algebras using asymptotic morphisms. The purpose of this paper is to further explore the class of connective C*-algebras. We give new characterizations of connectivity for exact and for nuclear separable C*-algebras and show that an extension of connective separable nuclear C*-algebras is connective. We establish connectivity or lack of connectivity for C*-algebras associated to certain classes of groups: virtually abelian groups, linear connected nilpotent Lie groups and linear connected semisimple Lie groups.

26 pages. A glitch in Definition 2.9 is corrected