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Electrochimica Acta
Article . 2019 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Dynamic electrochemical impedance spectroscopy of quasi-reversible redox systems. Properties of the Faradaic impedance, and relations to those of voltammograms

Authors: Pajkossy, Tamás;

Dynamic electrochemical impedance spectroscopy of quasi-reversible redox systems. Properties of the Faradaic impedance, and relations to those of voltammograms

Abstract

Abstract By analysing the electrochemical impedance spectra (EIS) of quasi-reversible redox systems, the two elements of the Faradaic impedance: charge transfer resistance and the coupled Warburg-coefficient can be obtained at a given potential. The same applies also to DEIS (dynamic EIS) measurements, when high frequency impedance spectra are measured while the potential is scanned to simultaneously accomplish cyclic voltammetry or other transient measurements. In case of DEIS both the charge transfer resistance and the Warburg coefficient depend on the applied potential program, e.g. on scan-rate. A theory is presented, yielding a transformation by which this dependence can be eliminated. The proposed procedure yields two, scan-rate independent, hysteresis-free functions, which are closely related to the EIS results, and also to the functions which are the transformed forms of the cyclic voltammograms as suggested in T. Pajkossy, S. Vesztergom, Electrochim. Acta, 297 (2019) 1121. To illustrate the properties of the transformations and the functions involved, numerical simulations are also presented. The theory opens a new route for the high-accuracy, fast determination of charge transfer rate coefficients of quasi-reversible redox systems by employing DEIS.

Country
Hungary
Keywords

QD02 Physical chemistry / fizikai kémia

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Top 10%
Top 10%
Top 10%
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