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Electrochimica Acta
Article . 2016 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 2. Capacitance

Authors: Alexander, Christopher L.; Tribollet, Bernard; Orazem, Mark E.;

Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 2. Capacitance

Abstract

Finite–element simulations were performed to determine the influence of a radial distribution of capacitance on the impedance of ideally polarized disk electrodes. The characteristic length associated with this form of distribution was found to be the period of the distribution. This work showed that while a capacitance distribution causes frequency dispersion, this effect is seen only at frequencies that are much higher than those associated with the disk-geometry-induced frequency dispersion. Thus, a constant-phase-element associated with a surface distribution of time constants cannot be attributed to a distribution of capacitance.

Country
France
Keywords

Frequency Dispersion, impedance spectroscopy, [CHIM.OTHE] Chemical Sciences/Other, capacitance, [CHIM] Chemical Sciences

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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
62
Top 10%
Top 10%
Top 10%
Green
bronze