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Magnesium Sulphide as Anode Material for Lithium-Ion Batteries

Authors: Helen, M.; Fichtner, M.;

Magnesium Sulphide as Anode Material for Lithium-Ion Batteries

Abstract

There is a great interest for alternative high capacity, low voltage anode materials in Li ion batteries. In an attempt towards this we report the investigation of magnesium sulphide (MgS) as sustainable anode material for lithium-ion batteries. The theoretical reaction potential of MgS with lithium is 0.5 V. It has a theoretical specific capacity of 951 mAh g-1 assuming the following reaction. MgS + 2Li ---> Li2S + Mg In addition, lithium can react with magnesium to form alloys of lithium by further increasing the theoretical capacity. The high capacity combined with low reaction potential makes MgS an interesting anode material for Li-ion batteries in principle. Hence we synthesized MgS-carbon nanocomposites and evaluated them as anode material for lithium-ion batteries. A possible lithiation and delithiation mechanism for MgS is proposed based on electrochemical and ex-situ XRD studies. The electrochemical reaction of MgS with lithium results in the formation of Li2S and Mg, the as-formed Mg simultaneously reacts with lithium and forms LixMg alloy further contributing to the capacity. A stable reversible capacity of 530 mAh g-1 was achieved after 100 cycles within the voltage window of 0.001 - 2.5 V (Figure 1). The compatibility of MgS anode was tested in full cell using lithium nickel manganese cobalt oxide (LNMC) and lithium iron phosphate (LFP) as cathodes. Figure 1

Country
Germany
Keywords

Technology, ddc:600, info:eu-repo/classification/ddc/600, 600

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    15
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Top 10%
Average
Top 10%
Green
bronze