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Computer Physics Communications
Article . 2007 . Peer-reviewed
License: Elsevier TDM
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Article . 2007
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https://dx.doi.org/10.48550/ar...
Article . 2006
License: arXiv Non-Exclusive Distribution
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DBLP
Article . 2007
Data sources: DBLP
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Are polymer melts “ideal”?

Authors: Wittmer, Joachim; Beckrich, Philippe; Crevel, Francois; Huang, C.C.; Cavallo, Anna; Kreer, Torsten; Meyer, Hendrik;

Are polymer melts “ideal”?

Abstract

It is commonly accepted that in concentrated solutions or melts high-molecular weight polymers display random-walk conformational properties without long-range correlations between subsequent bonds. This absence of memory means, for instance, that the bond-bond correlation function, $P(s)$, of two bonds separated by $s$ monomers along the chain should exponentially decay with $s$. Presenting numerical results and theoretical arguments for both monodisperse chains and self-assembled (essentially Flory size-distributed) equilibrium polymers we demonstrate that some long-range correlations remain due to self-interactions of the chains caused by the chain connectivity and the incompressibility of the melt. Suggesting a profound analogy with the well-known long-range velocity correlations in liquids we find, for instance, $P(s)$ to decay algebraically as $s^{-3/2}$. Our study suggests a precise method for obtaining the statistical segment length \bstar in a computer experiment.

4 pages, 3 figures

Country
France
Keywords

Macromolecular and polymer solutions, Soft Condensed Matter (cond-mat.soft), FOS: Physical sciences, Monte Carlo methods, Condensed Matter - Soft Condensed Matter, Polymer melts, [PHYS.COND.CM-SCM] Physics [physics]/Condensed Matter [cond-mat]/Soft Condensed Matter [cond-mat.soft]

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Average
Top 10%
Top 10%
Green
bronze