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Carbohydrate Polymers
Article . 2019 . Peer-reviewed
License: CC BY NC ND
Data sources: Crossref
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Carbohydrate Polymers
Article
License: CC BY NC ND
Data sources: UnpayWall
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Preparation of cellulose nanomaterials via cellulose oxalates

Authors: Jonatan Henschen; Monica Ek; Dongfang Li;

Preparation of cellulose nanomaterials via cellulose oxalates

Abstract

Nanocellulose prepared from cellulose oxalate has been discussed as an alternative to other methods to prepare cellulose nanofibrils or crystals. The current work describes the use of a bulk reaction between pulp and oxalic acid dihydrate to prepare cellulose oxalate followed by homogenization to produce nanocellulose. The prepared nanocellulose is on average 350 nm long and 3-4 nm wide, with particles of size and shape similar to both cellulose nanofibrils and cellulose nanocrystals. Films prepared from this nanocellulose have a maximum tensile stress of 140-200 MPa, strain at break between 3% and 5%, and oxygen permeability in the range of 0.3-0.5 cm3 μm m-2 day-1 kPa-1 at 50% relative humidity. The presented results illustrate that cellulose oxalates may be a low-cost method to prepare nanocellulose with properties reminiscent of those of both cellulose nanofibrils and cellulose nanocrystals, which may open up new application areas for cellulose nanomaterials.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
111
Top 1%
Top 10%
Top 1%
hybrid