Abstract BaTiO 3 is a type of ceramic with a high dielectric constant, while silicone is a type of elastomer with low elastic modules. Composites made by blending these two materials together can obtain both of their advantages, which has many possible applications in the area of actuators or mechanical sensors. In this study, to improve the dispersity of the BaTiO 3 particles, a novel silicone coupling agent was used to modify the surface of the particles. TG and FTIR results showed that the coupling agent was successfully coated on the surface. Raw BaTiO 3 and BaTiO 3 modified by the silicone coupling agent were incorporated into the silicone elastomer to fabricate the BaTiO 3 /silicone membranes. Particle size distribution measurements and SEM observations showed that the BT particles can obtain a higher compatibility with the silicone, and both the dispersity of the BaTiO 3 particles and the dielectric properties of the BaTiO 3 /silicone membranes were improved after the surface modification, even without a poling process during the fabrication or measurement. The measuring circuit containing the BaTiO 3 /silicone membrane is expected to have several applications such as mechanical sensors.