Consider nonlinear Choquard equations \begin{equation*} \left\{\begin{array}{rcl} -Δu +u & = &(I_α*F(u))F'(u) \quad \text{in } \mathbb{R}^N, \\ \lim_{x \to \infty}u(x) & = &0, \end{array}\right. \end{equation*} where $I_α$ denotes Riesz potential and $α\in (0, N)$. In this paper, we show that when $F$ is doubly critical, i.e. $F(u) = \frac{N}{N+α}|u|^{\frac{N+α}{N}}+\frac{N-2}{N+α}|u|^{\frac{N+α}{N-2}}$, the nonlinear Choquard equation admits a nontrivial solution if $N \geq 5$ and $α+ 4 < N$.