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Luminescence of Pr3+ in scandium borate (ScBo3) and the host lattice dependence of the stokes shift

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1989 English Publisher:Elsevier BVJournal:Journal of Physics and Chemistry of Solids, volume 50, pages 583-585 (issn: 0022-3697,

Authors: G. Blasse; R. Hoogendam; J.P.M. van Vliet; M. Wiegel; J.W.M. Verwey;

doi: 10.1016/0022-3697(89)90451-4

Luminescence of Pr3+ in scandium borate (ScBo3) and the host lattice dependence of the stokes shift

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Abstract

Abstract The luminescence of ScBO 3 −Pr 3+ is investigated. The emission consists of four spin-allowed transitions and one spin-forbidden transition from the 4 f ; 5 d to the 4 f ; 2 configuration. The Stokes shift is very small (1500cm −1 ). In YBO 3 and LaBO 3 this Stokes shift increases to 3000cm −1 ). These data are compared with those for Ce 3+ , Sb 3+ and Bi 3+ in these borates. This yields information on the dependence of the Stokes shift on the lattice. This can be used to make predictions. Here it is applied to glasses.

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