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Abstract The luminescence properties of Eu2+-activated alkaline earth haloborates M2B5O9X-Eu2+ (M = Ca, Sr, Ba; X = Cl, Br) have been studied. The influence of the host lattice cation and anion on the position of the lowest 4f65d excited state are explained on the basis of a crystal field effect and a nephelauxetic effect, respectively. The relaxation in the 4f65d excited state is shown to become more restricted with increasing radius of the alkaline earth ion in the host lattice by directly measuring the Stokes shift of the 4f6(7F0)5d emission. Energy transfer between the two inequivalent Eu2+ ions in the barium bromoborate is very efficient ( R c = 20 A ) and has been evaluated quantitatively.
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 151 | |
popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 1% | |
influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 1% | |
impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |