
Abstract The reaction of UF 4 with UN at 950°C yields UF 3 or UNF depending on the mixing ratio; the product is UF 3 for the UF 4 :UN ratio of 3:1, and UNF for 1:3. The reaction is generally expressed as x UF 4 (s)+y UN (s) → 3x − y 2 UF 3 (s)+ 3y−x 2 UNF(s)+ x−y 4 N 2 (g) . The free energy change for the formation of UF 3 is discussed on the basis of the experimental results.
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