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Luminescence of Zn4X and Cd4X clusters (X = S, Se) in an aluminate or borate cage

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1995 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 234, pages 177-181 (issn: 0009-2614,

Authors: M.E. Brenchley; G.J. Dirksen; M.T. Weller; G. Blasse;

doi: 10.1016/0009-2614(95)00022-v

Luminescence of Zn4X and Cd4X clusters (X = S, Se) in an aluminate or borate cage

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Abstract

Abstract The tetrahedral clusters Zn 4 X (X  O, Se) and Cd 4 X (X  S, Se) show efficient photoluminescence at room temperature in the sodalites Zn 4 X(BO 2 ) 6 and Cd 4 X(AlO 2 ) 6 , respectively. The lowest absorption band is at higher energy, and the Stokes shift is larger than in other Zn/Cd chalcogenide clusters.

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