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[Eu ⊂ bpy·bpy·bpy]+ cryptate: Luminescence and conformation

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1988 Italy English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 146, pages 347-351 (issn: 0009-2614,

Authors: Blasse, G.; Dirksen, G. J.; van der Voort, D.; Sabbatini, N.; Perathoner, S.; Lehn, J. -M.; Alpha, B.;

doi: 10.1016/0009-2614(88)87457-8

handle: 11570/3131392

[Eu ⊂ bpy·bpy·bpy]+ cryptate: Luminescence and conformation

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Abstract

Abstract The luminescence of [Eu ⊂ bpy·bpy·bpy] 3+ cryptate is reported for the solid (down to 4.2 K) and for molecules in porous glass. Energy transfer from the cryptand to Eu 3+ occurs with high efficiency. The emission spectra are used to evaluate the molecular conformation of the cryptate. The Eu 3+ ion appears to be off-centre.

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Italy

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1 Research products, page 1 of 1

Europium-bipyridine derivative ion(3+) ([Eu .cntnd. bpy·bpy·bpy]3+) cryptate: luminescence and conformation
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