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Jahn-Teller distortion in the excited state of tellurium(IV) in Cs2MCl6 (M=Zr, Sn)

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1988 English Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 144, pages 460-462 (issn: 0009-2614,

Authors: H. Donker; P.J.H. Drummen; G. Blasse; W.M.A. Smit;

doi: 10.1016/0009-2614(88)87296-8

Jahn-Teller distortion in the excited state of tellurium(IV) in Cs2MCl6 (M=Zr, Sn)

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Abstract

Abstract The luminescence spectra of the diluted systems Cs 2 ZrCl 6 :Te 4+ and Cs 2 SnCl 6 :Te 4+ are reported at liquid-helium and room temperature. The shape of the excitation spectrum of the Ten+ luminescence reveals a dynamic Jahn-Teller distortion in the excited state. At low temperatures the Te 4+ emission shows a vibrational progression in the e g mode. The same vibrational mode is derived from the temperature dependence of the splitting of the A excitation band. Vibrational structure is also observed in the B band of the excitation spectrum of Cs 2 SnCl 6 :Te 4+ .

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