New band systems of NiBr molecule in visible region

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1980 English Publisher:Springer Science and Business Media LLCJournal:Pramana, volume 15, pages 349-356 (issn: 0304-4289, eissn: 0973-7111,

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Authors: R Gopal; M M Joshi;

doi: 10.1007/bf02848593

New band systems of NiBr molecule in visible region

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Abstract

Thermal emission spectrum of NiBr molecule excited by vacuum graphite tube furnace revealed the existence of ten new band sub-systems in the region λλ 5540-4720 A which were attributed toA→X,B→X,C→X andD→X transitions. Vibrational analysis was carried out for each of the systems mentioned above.A 2 Δ has been suggested as the ground state of NiBr molecule with an electronic interval of about 533 cm−1. Transitions responsible for NiBr spectrum appear to be of the type2π–2Δ and2Δ–2Δ.

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University of Allahabad
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