The temperature dependence of the electrical conductivity, thermoelectric power and dielectric constant of the antiferromagnetic CuWO4 have been studied in the temperature range 300–1000 K. The conductivity results can be summarised by the equations σI=6.31 × 10−3 exp (−0.29 eV/kT) ohm−1 cm−1 in the temperature range 300–600 K and σII=3.16 × 105 exp (−1.48 eV/kT) ohm−1 cm−1 between 600 K and 1000 K. The thermoelectric power can be expressed byθ=[− 1.25 (103/T) + 3.9] mV/K. Initially dielectric constant increases slowly but for high temperatures its increase is fast.