Gas phase formation of methyl and ethyl iodides

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 1981 English Publisher:Springer Science and Business Media LLCJournal:Journal of Radioanalytical Chemistry, volume 65, pages 61-73 (issn: 0134-0719, eissn: 1588-2780,

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Authors: C.T. Peng;

doi: 10.1007/bf02516089 , 10.1016/0047-0740(82)90109-7

Gas phase formation of methyl and ethyl iodides

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Abstract

Gas phase formation of methyl and ethyl iodides occurs when methanol and ethanol vapors are carried by an inert gas over silica-alumina catalyst supports impregnated with potassium, sodium, cesium, or cadmium iodides at 130–180°. The efficiency of conversion of inorganic to organic iodides by different catalysts was studied using125I-labelled potassium and cadmium iodides. A mechanism of organic iodide formation in the heterogeneous reaction is postulated.

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University of California, San Francisco
United States

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