The accuracy of determining the kinetics constants and the law of linear compensation

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1979 English Publisher:Springer Science and Business Media LLCJournal:Journal of Thermal Analysis, volume 17, pages 549-553 (issn: 0368-4466,

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Authors: J. Norwisz; J. Plewa;

doi: 10.1007/bf01914045

The accuracy of determining the kinetics constants and the law of linear compensation

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Abstract

In the light of the data obtained concerning copper oxidation kinetics, the law of linear compensation:E=E0 + 2.303β logZ has been examined critically. By the use of different calculation techniques, the existence of a “compensation” dependence has been observed for different pairs of values of the activation energyE and the pre-exponential constantZ, obtained for the same set of experimental data.

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